Highly efficient heterogeneous photo-Fenton BiOCl/MIL-100(Fe) nanoscaled hybrid catalysts prepared by green one-step coprecipitation for degradation of organic contaminants

Abstract

An excellent heterojunction structure is vital for the improvement of photocatalytic performance. In this study, BiOCl/MIL-100(Fe) hybrid composites were prepared via a one-pot coprecipitation method for the first time. The prepared materials were characterized and then used as a photo-Fenton catalyst for the removal of organic pollutants in wastewater. The BiOCl/MIL-100(Fe) hybrid exhibited better photo-Fenton activity than MIL-100(Fe) and BiOCl for RhB degradation; in particular, the hybrid with 50% Bi molar concentration showed the highest efficiency. The excellent performance can be ascribed to the presence of coordinatively unsaturated iron centers, abundant Lewis acid sites, fast H₂O₂ activation, and efficient carrier separation on BiOCl nanosheets due to the high charge carrier mobility of the nanosheets. The photo-Fenton mechanism was studied, and the results indicated that ˙OH and h⁺ were the main active species for organic pollutant degradation. The coprecipitation-based hybridization approach presented in this paper opens up an avenue for the sustainable fabrication of photo-Fenton catalysts with abundant coordinatively unsaturated metal centers and efficient electron–hole separation capacity.