Optimization study on deep extractive oxidative desulfurization with tetrabutylammonium bromide/polyethylene glycol DES

Abstract

Green, efficient and inexpensive desulfurizing solvents have always been a considerable focus of petroleum desulfurization research. In this study, a series of deep eutectic solvents (DESs) based on tetrabutylammonium bromide (TBAB)/polyethylene glycol 200 (PEG-200) with different molar ratios were synthesized and characterized by Fourier transform infrared spectroscopy and ¹H nuclear magnetic resonance spectroscopy. Dibenzothiophene (DBT) was removed deeply as the classic sulfide in model oil, and H₂O₂ was fully utilized by the new TBAB/PEG-200 desulfurization system in step extractive oxidative desulfurization. The reaction conditions were optimized further, and O/S = 8, DES/oil = 1 : 5, 40 °C and 75 minutes were chosen as the best reaction conditions. Meanwhile, other organic sulfides in crude oil were also removed, and the removal rates of DBT, 4,6-dimethyldibenzothiophene and benzothiophene were 99.65%, 96.71% and 93.52%, respectively. The DES was reused 7 times, and the desulfurization efficiency of the regenerated DES for DBT was maintained at 98.14%. Finally, the possible mechanism of the synergistic effect of two kinds of hydrogen bonds and the oxidant was proposed.