The selective recognition mechanism of a novel highly hydrophobic ion-imprinted polymer towards Cd(ii) and its application in edible vegetable oil

Abstract

Edible vegetable oils are easily contaminated by heavy metals, resulting in the oxidative degradation of oils and various health effects on humans. Therefore, it is very important to develop a rapid and efficient method to extract trace heavy metals from vegetable oils. In this work, a highly hydrophobic ion-imprinted polymer (IIP) was synthesized on a novel raspberry (RS)-like particle surface. The synthesized IIP@RS was characterized and used in solid-phase extraction (SPE) for the selective and fast adsorption of Cd(II) from vegetable oils. The results showed that IIP was successfully coated onto RS particles with a high specific surface area (458.7 m² g⁻¹) and uniform porous structure. The contact angle (θ) value (141.8°) of IIP@RS was close to the critical value of super-hydrophobic materials, which is beneficial to their adsorption in hydrophobic vegetable oils. The IIP@RS also exhibited excellent adsorption ability and selectivity to Cd(II) with a maximum adsorption capacity of 36.62 mg g⁻¹, imprinting factor of 4.31 and equilibrium adsorption rate of 30 min. According to isothermal titration calorimetry results, the recognition behavior of IIP@RS for Cd(II) was mainly contributed by Cd(II)-induced cavities during gel formation and coordination between Cd(II) and –SH groups in imprinted cavities. Furthermore, the adsorption process driven by entropy and enthalpy was spontaneous at all temperatures. In real vegetable oil samples, IIP@RS-SPE adsorbed approximately 96.5–115.8% of Cd(II) with a detection limit of 0.62 μg L⁻¹. Therefore, IIP@RS has wide application prospects in enriching and detecting Cd(II) from vegetable oil.