Bioinspired pressure-sensitive adhesive: evaluation of the effect of dopamine methacrylamide comonomer as a general property modifier using molecular dynamics simulation

Abstract

The use of catechol-containing comonomers as a general property enhancer to achieve unique properties has received particular attention for designing bioinspired polymeric materials. In this study, molecular dynamics simulation was used to investigate the role of dopamine methacrylamide (DMA) and N-phenethyl methacrylamide (PMA) comonomers in chain conformation and their effects on the mechanical properties and adhesion of poly(n-butyl acrylate-co-acrylic acid) copolymer. Addition of 4% by weight of DMA comonomer in the terpolymer structure reduces the gyration radius of the poly(n-butyl acrylate-co-acrylic acid) copolymer. This reduction is due to the formation of intramolecular hydrogen bond interactions. A further increase in the DMA up to 12.2% by weight increases the radius of gyration by 5%. The effect of PMA on the gyration radius of the poly(n-butyl acrylate-co-acrylic acid) copolymer is more extensive, compared to DMA. While DMA enhances both van der Waals and electrostatic components of the cohesive energy density through increasing π–π interactions and hydrogen bond formations, PMA only improves the van der Waals component. Assessment of mechanical properties revealed that the addition of DMA comonomer resulted in a transition from brittle to tough behavior in poly(n-butyl acrylate-co-acrylic acid) pressure-sensitive adhesive. Ductility index improvement by DMA is higher than that by PMA. DMA comonomers accumulate on the silica surface resulting in the terpolymer chains approaching the dry silica surface from the hydroxyl groups of the catechol. Accumulation of DMA only enhances the cohesive energy and does not improve the adhesive energy.