A simple method for the preparation of a nickel selenide and cobalt selenide mixed catalyst to enhance bifunctional oxygen activity for Zn–air batteries

Abstract

Developing a low-cost, simple, and efficient method to prepare excellent bifunctional electrocatalysts toward the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical in rechargeable zinc–air batteries. Non-stoichiometric M_0.85Se (M = Ni or Co) nanoparticles are synthesized and modified on nitrogen-doped hollow carbon sphere (NHCS). The NHCS loaded Ni_0.85Se (Ni_0.85Se-NHCS) with rich Ni³⁺ presents higher OER activity, whereas the NHCS-loaded Co_0.85Se (Co_0.85Se-NHCS) with abundant Co²⁺ displays better ORR activity, respectively. When Co_0.85Se-NHCS is mixed with Ni_0.85Se-NHCS in a mass ratio of 1 : 1, the resulting mixture (Ni_0.85Se/Co_0.85Se-NHCS-2) shows better ORR and OER dual catalytic functions than a single selenide. Moreover, zinc–air batteries equipped with Ni_0.85Se/Co_0.85Se-NHCS-2 as the oxygen electrode catalyst exhibit excellent charge and discharge performance as well as improved stability over precious metals. This work has developed a simple and effective method to prepare excellent bifunctional electrocatalysts for ORR and OER, which is beneficial for the practical large-scale application of zinc–air batteries.