Issue 22, 2021, Issue in Progress
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RSC Advances

Catalytic enantioselective bromohydroxylation of cinnamyl alcohols†

Jing Li ORCID logo a  and  Yian Shi*ab  

* Corresponding authors

a Institute of Natural and Synthetic Organic Chemistry, Changzhou University, Changzhou 213164, P. R. China
E-mail: shiyian@cczu.edu.cn

b Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA

Abstract

This work describes an effective enantioselective bromohydroxylation of cinnamyl alcohols with (DHQD)2PHAL as the catalyst and H2O as the nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.

Graphical abstract: Catalytic enantioselective bromohydroxylation of cinnamyl alcohols

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Article information

DOI
https://doi.org/10.1039/D1RA02297K
Article type
Paper
Submitted
23 Mar 2021
Accepted
23 Mar 2021
First published
07 Apr 2021
This article is Open Access
Creative Commons BY license

RSC Adv., 2021,11, 13040-13046

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Catalytic enantioselective bromohydroxylation of cinnamyl alcohols

J. Li and Y. Shi, RSC Adv., 2021, 11, 13040 DOI: 10.1039/D1RA02297K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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