Issue 11, 2021

Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units

Abstract

A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded π-conjugated backbone has been synthesized and characterized. This promising photo- and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acceptor system. Our studies show its self-assembly resulting from aggregation via π–π stacking interaction in solution and in the solid state.

Graphical abstract: Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units

Supplementary files

Article information

Article type
Paper
Submitted
12 Jan 2021
Accepted
25 Jan 2021
First published
03 Feb 2021
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2021,11, 6002-6007

Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units

C. Drou, T. Merland, A. Busseau, S. Dabos-Seignon, A. Goujon, P. Hudhomme, L. Benyahia, C. Chassenieux and S. Legoupy, RSC Adv., 2021, 11, 6002 DOI: 10.1039/D1RA00287B

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