Degradation of textile dyes from aqueous solution using tea-polyphenol/Fe loaded waste silk fabrics as Fenton-like catalysts

Abstract

In this study, waste silk fabrics (SF) were modified with tea-polyphenols (TPs) and then iron (Fe²⁺). The modified silk fabrics (TP-SF/Fe) were characterized via Fourier-transform infrared (FTIR), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) analysis. TP-SF/Fe was used in the Fenton-like removal of dyes (methylene blue, reactive orange GRN, and cationic violet X-5BLN) from aqueous solutions with catalyst-like activity. The effects of different catalyst samples, contact time, H₂O₂ concentration, initial dye concentration, and pH values on dye removal were investigated. The results showed that the dye removal percentages with the TP-SF/Fe-H₂O₂ sample reached 98%, 97%, and 95% in 5–40 min for methylene blue, reactive orange GRN, and cationic violet X-5BLN, respectively. Different thermodynamic and kinetic models were used to check the best fit of the adsorption data. The results indicated that the Freundlich isotherm and pseudo first-order kinetics models were the best fits. Moreover, it was also proved that TP-SF/Fe would be quite an effective and economical adsorbent for the treatment of textile dye wastewater. This work provides the basis for waste silk application in the removal of dyes from wastewater.