Mechanical power driven SPME-SERS ultra-fast detection of illegal additives in aquaculture water

Abstract

A dual-function (extraction and detection) porous silver fiber with high enhancement effect was constructed based on a convenient electrochemical etching method. The prepared silver fiber not only had high enrichment capacity and good Surface Enhanced Raman Spectroscopy (SERS) performance but also had good laser stability and uniformity. A strategy combining mechanical power and integration of solid phase extraction (SPME) and SERS detection was used. Driven by mechanical power, the analyte malachite green (MG) was enriched on the prepared silver fiber after 40 seconds, which can realize an ultra-fast and sensitive detection with a detection limit of 8.48 × 10⁻⁹ M. At the same time, this fiber can be regenerated after being treated with NaBH₄. The silver fiber can be used for the detection of MG and CV after being immersed in NaBH₄ solution for a few minutes. After 5 cycles of processing, the measurement signals of the silver fiber can reach 70% of the initial signals. The mechanical power driven SPME-SERS (MPD-SPME-SERS) integrated detection method can be used to analyse aquaculture water within 1 minute with a good linear relationship.