Despite limited reports employing sustainable solvents for Direct Arylation Polymerization (DArP), the large amount of organic waste generated from conjugated polymer synthesis requires attention. Herein, we report the first emulsion-DArP methodology to afford polymers with molecular weights up to 14.5 kg mol−1 with a 10-fold reduction of organic solvent utilized.
L. Ye, T. Hooshmand and B. C. Thompson, Polym. Chem., 2021, 12, 6688 DOI: 10.1039/D1PY01321A
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