Issue 45, 2021

[6 + 3] Annulations of Morita–Baylis–Hillman carbonates and dicyanoheptafulvene

Abstract

A [6 + 3] annulation reaction of Morita–Baylis–Hillman carbonates and dicyanoheptafulvene is accomplished by employing commercially available triphenylphosphine as the Lewis base catalyst. A spectrum of densely functionalized bicyclo[4.3.1]decane architectures are efficiently constructed with exclusive diastereoselectivity and good yield (up to 95%).

Graphical abstract: [6 + 3] Annulations of Morita–Baylis–Hillman carbonates and dicyanoheptafulvene

Supplementary files

Article information

Article type
Paper
Submitted
04 May 2021
Accepted
26 Oct 2021
First published
28 Oct 2021

Org. Biomol. Chem., 2021,19, 9867-9871

[6 + 3] Annulations of Morita–Baylis–Hillman carbonates and dicyanoheptafulvene

R. Jia, Q. Liu, L. Yang, S. Deng and Y. Song, Org. Biomol. Chem., 2021, 19, 9867 DOI: 10.1039/D1OB00854D

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