Issue 23, 2021
From the journal:

Organic & Biomolecular Chemistry

A nickel-catalyzed silylation reaction of alkyl aryl sulfoxides with silylzinc reagents†

Wei-Ze Lia  and  Zhong-Xia Wang ORCID logo *ab  

* Corresponding authors

a CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
E-mail: zxwang@ustc.edu.cn
Tel: +86 551 63603043

b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, P. R. China

Abstract

Ni(PEt3)Cl2-catalyzed silylation of alkyl aryl sulfoxides with silylzinc reagents was carried out. This protocol allows alkyl aryl sulfoxides to convert to arylsilicon compounds under mild reaction conditions, tolerates a range of functional groups and is suitable for a wide scope of substrates.

Graphical abstract: A nickel-catalyzed silylation reaction of alkyl aryl sulfoxides with silylzinc reagents

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Article information

DOI
https://doi.org/10.1039/D1OB00840D
Article type
Communication
Submitted
29 Apr 2021
Accepted
18 May 2021
First published
19 May 2021

Org. Biomol. Chem., 2021,19, 5082-5086

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A nickel-catalyzed silylation reaction of alkyl aryl sulfoxides with silylzinc reagents

W. Li and Z. Wang, Org. Biomol. Chem., 2021, 19, 5082 DOI: 10.1039/D1OB00840D

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