Itaconic acid esters and hemiesters undergo Pd-catalyzed coupling reactions with arene diazonium salts in high to excellent yields. The coupling products of ortho-nitro arene diazonium salts can be converted in one or two steps to benzazepine-2-ones.
A. Krause, E. Sperlich and B. Schmidt, Org. Biomol. Chem., 2021, 19, 4292 DOI: 10.1039/D1OB00392E
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