Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles

Masaki Kobayashi; Hiroki Yamaguchi; Takeyuki Suzuki; Yasushi Obora

doi:10.1039/D1OB00045D

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Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles†

Masaki Kobayashi,^a Hiroki Yamaguchi,^a Takeyuki Suzuki

^b and Yasushi Obora

*^a

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* Corresponding authors

^a Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
E-mail: obora@ kansai-u.ac.jp
Fax: +81-6-6339-4026
Tel: +81-6-6368-0876

^b Comprehensive Analysis Center, The Institute of Scientific and Industrial Research (ISIR), Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0057, Japan

Abstract

A simple method for the cross β-alkylation of linear alcohols with benzyl alcohols in the presence of DMF-stabilized iridium nanoparticles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity.

This article is part of the themed collections: Synthetic methodology in OBC and Catalysis & biocatalysis in OBC

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Article information

DOI: https://doi.org/10.1039/D1OB00045D
Article type: Communication
Submitted: 09 Jan 2021
Accepted: 08 Feb 2021
First published: 08 Feb 2021

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Org. Biomol. Chem., 2021,19, 1950-1954

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Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles

M. Kobayashi, H. Yamaguchi, T. Suzuki and Y. Obora, Org. Biomol. Chem., 2021, 19, 1950 DOI: 10.1039/D1OB00045D

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Organic & Biomolecular Chemistry

Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles†

Abstract

Supplementary files

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Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles

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