NiCo LDH in situ derived NiCoP 3D nanoflowers coupled with a Cu3P p–n heterojunction for efficient hydrogen evolution

Abstract

With the extensive consumption of non-renewable energy sources, storing solar energy as chemical energy has aroused people's wide concern. In this study, we successfully developed a novel Cu₃P@NiCoP composite photocatalyst to produce hydrogen by splitting water under visible light irradiation. Both the building of a p–n heterojunction between Cu₃P and NiCoP and the three-dimensional nanoflower structure of NiCoP play a vital role in improving the performance of the catalyst. On the one hand, the coupling of Cu₃P and NiCoP built a p–n heterojunction at the photocatalyst interface, and the heterojunction could promote the separation efficiency of photogenerated carriers and prolong the life span of charges, therefore enhancing the photocatalytic hydrogen production activity. On the other hand, the excellent catalytic performance of the photocatalyst was benefited by the flower-like microsphere structure of NiCoP, which could provide abundant active sites and a large specific surface area, and promote the adsorption of protons by the photocatalyst. Besides, the phosphating degree of the precursors and the ratio of Cu₃P and NiCoP were adjusted to get the best photocatalyst for hydrogen production, and the H₂ production of the optimal catalyst could reach 8897.44 μmol h⁻¹ g⁻¹. This work provides a new understanding for the rational design of heterojunction photocatalysts for outstanding hydrogen production performance.