Surface plasmonic resonance tunable nanocomposite thin films applicable to color filters, heat mirrors, semi-transparent electrodes, and electromagnetic-shields

Abstract

This study proposes a plasmonic resonance–tunable nanocomposite thin film, which applies to a color filter, heat mirror, semi-transparent color electrode, and electromagnetic shield, given that the size and structure of nanoclusters can be controlled by a sputtering power density. The structural and functional properties of silver/plasma-polymer-fluorocarbon (Ag/PPFC) nanocomposite thin films, which were sputtered by ternary composite targets, were investigated with various compositions and sputtering power densities. The growth of Ag nanoclusters of the thin film was suppressed as the sputtering power density increased due to the rich functional group of –CF_x– fluorine. As a result, a continuous color change from blue to yellow could be expressed on films given the precise control of the surface plasmonic resonance phenomenon. Grazing-incidence small-angle scattering (GISAXS) analysis indicated that the sputtering power density had a significant effect on the size, distribution, and orientation of the Ag nanoclusters in the thin film. For low sputtering power densities, Ag nanoclusters were forming aggregations along the out-of-plane direction, but as the sputtering power density increased, the nanoclusters showed random distribution instead of large aggregates. We also demonstrated applications of Ag/PPFC nanocomposite thin films to a color filter, heat mirror, semi-transparent electrode, and electromagnetic shield. In addition, the fabrication of a large-area film (400 × 700 mm²) showed that the approach applies highly to industries.