Issue 43, 2021

Radical-mediated aerobic oxidation of substituted styrenes and stilbenes

Abstract

A 2,2-azobis(isobutyronitrile)-catalyzed oxidative cleavage of alkenes with molecular oxygen as the oxidant was described. Carbonyl compounds and oxiranes were obtained in moderate yield under mild conditions. This study provided useful insights into the mechanism of aerobic oxidative cleavage of alkenes.

Graphical abstract: Radical-mediated aerobic oxidation of substituted styrenes and stilbenes

Supplementary files

Article information

Article type
Communication
Submitted
05 Oct 2021
Accepted
19 Oct 2021
First published
21 Oct 2021

New J. Chem., 2021,45, 20103-20106

Radical-mediated aerobic oxidation of substituted styrenes and stilbenes

H. Aman, W. Chiu, P. Liu and G. J. Chuang, New J. Chem., 2021, 45, 20103 DOI: 10.1039/D1NJ04755H

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