Highly selective oxidation of monosaccharides to sugar acids at room temperature over palladium supported on surface functionalized carbon nanotubes

Abstract

The selective oxidation of monosaccharides into sugar acids is an important reaction for the production of biomass-based chemicals, but the design of an efficient catalyst remains a big challenge. Herein we report a series of efficient and stable surface functionalized carbon nanotube supported palladium catalysts for the selective oxidation of monosaccharides into sugar acids at room temperature. The palladium nanoparticles supported on alkaline carbon nanotubes (Pd/CNT-N) showed the highest reaction activity. The maximum gluconic acid yield of 98.3% and xylonic acid yield of 95.8% were obtained at 30 °C within 180 min. DFT calculations revealed that the mechanism of xylose oxidation to xylonic acid involved the activation of OH⁻, adsorption of xylose, dissociation of the formyl C–H bond in xylose, formation of chemisorbed xylonic acid, and desorption of xylonic acid. The activation energy barrier for xylose oxidation over Pd/CNT-N is lower than that of Pd/CNT-O, explaining that the basic groups on CNT are more beneficial for accelerating monosaccharide oxidation and enhancing the sugar acid selectivity. This work not only presents a new facile route to produce sugar acid at room temperature, but also provides a basis to design and develop efficient catalysts with surface functionalized supports for various catalytic reactions.