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C(sp3)–H bond functionalization with styrenes via hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis

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Abstract

The redox-neutral addition of α-C–H bonds of acetonitrile and acetone to styrenes was enabled via the hydrogen-atom transfer from relatively acidic and water-miscible C(sp3)–H bonds to an aqueous hydroxyl radical generated cleanly and iteratively by the oxidation of water under silver-nanoparticle-loaded titania photocatalysis without using stoichiometric oxidation agents.

Graphical abstract: C(sp3)–H bond functionalization with styrenes via hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis

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Article information


Submitted
28 Feb 2021
Accepted
07 Apr 2021
First published
07 Apr 2021

Green Chem., 2021, Advance Article
Article type
Communication

C(sp3)–H bond functionalization with styrenes via hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis

S. Mori and S. Saito, Green Chem., 2021, Advance Article , DOI: 10.1039/D1GC00753J

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