Issue 4, 2021

Dehydrative allylation of P–H species under metal-free conditions

Abstract

An environmentally benign protocol for C–P bond construction was developed under metal- and solvent-free conditions. In the presence of B(C6F5)3, wide-spectrum P–H species, including dialkylphosphite, hypophosphite ester, and secondary phosphine oxides, can be successfully incorporated into the dehydrative cross-coupling process with allylic alcohols delivering the corresponding allylic organophosphorus compounds in high yields.

Graphical abstract: Dehydrative allylation of P–H species under metal-free conditions

Supplementary files

Article information

Article type
Communication
Submitted
18 Jan 2021
Accepted
08 Feb 2021
First published
09 Feb 2021

Green Chem., 2021,23, 1633-1637

Dehydrative allylation of P–H species under metal-free conditions

X. Yang, B. Li, H. Xing, J. Qiu, T. Loh and P. Xie, Green Chem., 2021, 23, 1633 DOI: 10.1039/D1GC00191D

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