Multiple rotor modes and how to trigger them: complex cation ordering in the family of relaxing hybrid formates

Paulina Peksa; Andrzej Nowok; Anna Gągor; Mirosław Mączka; Marek Drozd; Adam Sieradzki

doi:10.1039/D1DT03333F

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Multiple rotor modes and how to trigger them: complex cation ordering in the family of relaxing hybrid formates†

Paulina Peksa,^a Andrzej Nowok,

*^b Anna Gągor,^c Mirosław Mączka,

^c Marek Drozd

^c and Adam Sieradzki

*^a

Author affiliations

* Corresponding authors

^a Department of Experimental Physics, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
E-mail: adam.sieradzki@pwr.edu.pl

^b Institute of Physics, University of Silesia, ul. 75 Pułku Piechoty 1, 41-500 Chorzów, Poland
E-mail: andrzej.nowok@smcebi.edu.pl

^c Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Box 1410, 50-950 Wrocław, Poland

Abstract

A combination of structural, dielectric and calorimetric studies is used to describe a highly atypical behaviour of novel hybrid formate [NH₃(CH₂)₃NH₂(CH₂)₃NH₃][Mn(HCOO)₃]₃, incorporating large triprotonated molecular cations. Two successive phase transitions, switching between fast multiple rotor modes, and the surprising probable coexistence of static and dynamic disorder are discussed for this compound.

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Article information

DOI: https://doi.org/10.1039/D1DT03333F
Article type: Communication
Submitted: 01 Oct 2021
Accepted: 19 Nov 2021
First published: 19 Nov 2021
This article is Open Access

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Dalton Trans., 2021,50, 17906-17910

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Multiple rotor modes and how to trigger them: complex cation ordering in the family of relaxing hybrid formates

P. Peksa, A. Nowok, A. Gągor, M. Mączka, M. Drozd and A. Sieradzki, Dalton Trans., 2021, 50, 17906 DOI: 10.1039/D1DT03333F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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Multiple rotor modes and how to trigger them: complex cation ordering in the family of relaxing hybrid formates†

Abstract

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Multiple rotor modes and how to trigger them: complex cation ordering in the family of relaxing hybrid formates

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