A square planar silylene nickel four-membered ring

Abstract

Herein the new nickel silylene [PhC(NtBu)₂SiNi(C₅Me₅)]₂, which features a square planar central ring motif consisting of two silicon and two nickel atoms is presented. The title compound was obtained by an insertion of the Ni(0) precursor [Ni(cod)₂] (cod = 1,5-cyclooctadiene) in the Si–C bond of the silylene [PhC(NtBu)₂Si(C₅Me₅)]. Analytic characterisation including mass spectrometry as well as IR and Raman spectroscopies was combined with quantum chemical calculations to get an insight on the bonding situation within the four-membered Si–Ni-ring.