Ferrocenyl-terminated polyphenylene-type “click” dendrimers as supports for efficient gold and palladium nanocatalysis

Abstract

Although dendrimer supports have been known as key parts of nanocatalysts, the capability of rigid dendrimers for this function has not yet been reported. Here, the study is focused on ferrocenylmethylenetriazolyl-terminated dendrimers (FcMTPD) as supports of remarkably efficient nanogold and nanopalladium catalysts. A biphasic system is elaborated to evaluate the catalytic activity of FcMTPD-supported Au and Pd nanoparticles (NPs) for the reduction of 4-nitrophenol to 4-aminophenol by NaBH₄ at 20 °C, and FcMTPD-supported PdNPs are found to be the best nanocatalysts with a rate constant k_app = 7.8 × 10⁻² s⁻¹. Excellent catalytic results are also obtained in this reaction for FcMTPD-supported AuNPs with a rate constant k_app = 5.6 × 10⁻² s⁻¹. For both Pd NPs and AuNPs, the kinetic results are shown to strongly depend on the method of preparation of these NPs that influences the NP size and thus their catalytic efficiency. The FcMTPD-stabilized PdNPs are easily recovered and reused at least 13 times, and their catalytic performance displays only a slight decrease during the first seven runs.