Issue 27, 2021
From the journal:

Dalton Transactions

Benzyne addition to a metal–carbon multiple bond†

Harrison J. Barnett ORCID logo a  and  Anthony F. Hill ORCID logo ‡*a  

* Corresponding authors

a Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, Australia
E-mail: a.hill@anu.edu.au

Abstract

The linear μ-carbido complex [Rh2(μ-C)Cl2(dppm)2] (dppm = bis(diphenylphosphino)methane) reacts with a benzyne equivalent (Me3SiC6H4OTf-2/F−) to afford [Rh2(μ-CC6H4)(μ-Cl)(C6H5)Cl2(μ-dppm)2], in which the benzyne moiety adds across one of the two metal–carbon double bonds.

Graphical abstract: Benzyne addition to a metal–carbon multiple bond

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Article information

DOI
https://doi.org/10.1039/D1DT01402A
Article type
Communication
Submitted
28 Apr 2021
Accepted
22 Jun 2021
First published
25 Jun 2021

Dalton Trans., 2021,50, 9383-9387

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Benzyne addition to a metal–carbon multiple bond

H. J. Barnett and A. F. Hill, Dalton Trans., 2021, 50, 9383 DOI: 10.1039/D1DT01402A

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