Anionic oxoborane and thioxoborane molecules supported by a 1,2-bis(imino)acenaphthene ligand

Rui Liu; Fangfang Gao; Jingjing Liu; Jing Wei; Lei Hou; Gang Xie; Sanping Chen; Fanlong Zeng; Anyang Li; Wenyuan Wang

doi:10.1039/D1DT01060C

Anionic oxoborane and thioxoborane molecules supported by a 1,2-bis(imino)acenaphthene ligand†

Rui Liu,‡^a Fangfang Gao,‡^a Jingjing Liu,^a Jing Wei,^a Lei Hou,

^a Gang Xie,^a Sanping Chen,

^a Fanlong Zeng,

^a Anyang Li

*^a and Wenyuan Wang

*^a

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* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China
E-mail: liay@nwu.edu.cn, wangwy@nwu.edu.cn

Abstract

The isolable anionic oxoborane 3 and thioxoborane 4 have been assembled using a 1,2-bis(imino)acenaphthene ligand (Dip-BIAN). Structural characterization and DFT calculations confirmed that two compounds contain terminal doubly bonded B [double bond, length as m-dash] E (E = O, S) groups, respectively, in which only the BO group is associated with imidazolium via a hydrogen bond.

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Anionic oxoborane and thioxoborane molecules supported by a 1,2-bis(imino)acenaphthene ligand†

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Anionic oxoborane and thioxoborane molecules supported by a 1,2-bis(imino)acenaphthene ligand

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