Water-stable lanthanide–organic macrocycles from a 1,2,4-triazole-based chelate for enantiomeric excess detection and pesticide sensing

Abstract

Water-stable anionic Ln₂L₂-type (Ln = La^III and Eu^III) lanthanide–organic macrocycles have been constructed by deprotonation self-assembly of a bis-tridentate ligand consisting of two 2,6-bis-(1,2,4-triazole)-pyridine chelation arms bridged by a dibenzofuran chromophore, of which the luminescent Eu₂L₂ macrocycle can be used for enantiomeric excess (ee) detection toward pybox-type chiral ligands and selective colorimetric sensing of omethoate (OMA) in water.