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Issue 16, 2021
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Electrolytic synthesis of porphyrinic Zr-metal–organic frameworks with selective crystal topologies

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Abstract

The thermodynamic (PCN-222) and kinetic (PCN-224) products of porphyrinic Zr-metal–organic frameworks (MOFs) were synthesized via an anodic dissolution approach for the first time. To the best of our knowledge, this is the first report of MOF polymorphs being controlled by electrolysis. The selective formation of PCN-222 requires an amorphous component to be present on the electrode during the initial reaction process.

Graphical abstract: Electrolytic synthesis of porphyrinic Zr-metal–organic frameworks with selective crystal topologies

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Article information


Submitted
13 Feb 2021
Accepted
25 Mar 2021
First published
25 Mar 2021

Dalton Trans., 2021,50, 5411-5415
Article type
Communication

Electrolytic synthesis of porphyrinic Zr-metal–organic frameworks with selective crystal topologies

K. Okada, Y. Tanaka, T. Inose, H. Ujii, H. Yoshikawa and D. Tanaka, Dalton Trans., 2021, 50, 5411
DOI: 10.1039/D1DT00491C

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