Versatile oxalato-bridging modes: a novel three-dimensional framework structure of manganese(II) oxalate complex [MnC2O4]·0.5H2O and the relationship with other manganese(II) oxalates

Wen-Yuan Wu; Tie-Huan Tang; Yi Li; Shuang Xu

doi:10.1039/D0DT03765F

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Versatile oxalato-bridging modes: a novel three-dimensional framework structure of manganese(ii) oxalate complex [MnC₂O₄]·0.5H₂O and the relationship with other manganese(ii) oxalates†

Wen-Yuan Wu,

*^a Tie-Huan Tang,^a Yi Li^a and Shuang Xu^a

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* Corresponding authors

^a College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211800, China
E-mail: wwy@njtech.edu.cn

Abstract

An unknown manganese(II) oxalate complex [MnC₂O₄]·0.5H₂O (1) was discovered with a novel three-dimensional structure, exhibiting versatile bridging modes of the oxalate ligand. The thermal and magnetic behaviors of this complex were studied and the relationship with four other manganese(II) oxalates is also discussed.

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Article information

DOI: https://doi.org/10.1039/D0DT03765F
Article type: Communication
Submitted: 02 Nov 2020
Accepted: 02 Dec 2020
First published: 09 Dec 2020

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Dalton Trans., 2021,50, 485-489

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Versatile oxalato-bridging modes: a novel three-dimensional framework structure of manganese(II) oxalate complex [MnC₂O₄]·0.5H₂O and the relationship with other manganese(II) oxalates

W. Wu, T. Tang, Y. Li and S. Xu, Dalton Trans., 2021, 50, 485 DOI: 10.1039/D0DT03765F

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