Acid rain formation through catalytic transformation of sulfur dioxide over clay dusts: remarkable promotion by a vicinal aluminium site

Abstract

Catalytic SO₂ transformation over clay dusts is crucial for acid rain formation. Clay edges trigger chemisorption of ozone, which reacts directly with SO₂ instead of decomposing. A vicinal Al³⁺ site remarkably promotes adsorption and transformation, efficiently utilizing all O atoms in ozone (especially molecular oxygen) and producing three equivalents of H₂SO₄.