Can bulk nanobubbles be stabilized by electrostatic interaction?

Abstract

It has been suggested that electrostatic stress arising from charges accumulated at the surface of nanobubbles might balance Laplace pressure leading to their stability. This mechanism has been widely discussed in the nanobubble field for the past decade. However, the stress in the diffusive double layer was overlooked when calculating the electrostatic effect in previous theories. In this communication, we recalculated this effect using the classical double layer theory. Combined with experimentally measured zeta potential, we find that the ratio of electrostatic pressure to Laplace pressure is much less than 10⁻², which suggests that electrostatic interaction may not be the main factor for stabilizing bulk nanobubbles.