Issue 84, 2021

Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

Abstract

Mn cage complexes are rare, and the ones successfully isolated in the solid state are not stable in water and organic solvents. Herein, we present the first report of mononuclear Mn clathrochelates, in which the encapsulated metal exists in the oxidation state +4. The complexes are extremely stable in the crystalline state and in solutions and show rich redox chemistry.

Graphical abstract: Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2021
Accepted
28 Sep 2021
First published
28 Sep 2021

Chem. Commun., 2021,57, 11060-11063

Expanding manganese(IV) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

S. I. Shylin, J. L. Pogrebetsky, A. O. Husak, D. Bykov, A. Mokhir, F. Hampel, S. Shova, A. Ozarowski, E. Gumienna-Kontecka and I. O. Fritsky, Chem. Commun., 2021, 57, 11060 DOI: 10.1039/D1CC04870H

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