Issue 91, 2021
From the journal:

Chemical Communications

Redox-induced reversible P–P coupling in a uranium complex†

Wei Fang,a   Ambre Carpentier,b   Xiong Sun,a   Yue Zhao, ORCID logo a   Laurent Maron ORCID logo *b  and  Congqing Zhu ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
E-mail: zcq@nju.edu.cn

b LPCNO, CNRS & INSA, Université Paul Sabatier, 135 Avenue de Rangueil, 31077 Toulouse, France
E-mail: laurent.maron@irsamc.ups-tlse.fr

Abstract

A synthesized redox-active multidentate N–P ligand reacted with UCl4 in the presence of KHMDS or nBuLi, where two novel U(IV) complexes with or without P–P coupling were formed, respectively. The reversible P–P coupling in these complexes was observed in redox-induced reactions.

Graphical abstract: Redox-induced reversible P–P coupling in a uranium complex

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Article information

DOI
https://doi.org/10.1039/D1CC04765E
Article type
Communication
Submitted
26 Aug 2021
Accepted
26 Oct 2021
First published
30 Oct 2021

Chem. Commun., 2021,57, 12175-12178

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Redox-induced reversible P–P coupling in a uranium complex

W. Fang, A. Carpentier, X. Sun, Y. Zhao, L. Maron and C. Zhu, Chem. Commun., 2021, 57, 12175 DOI: 10.1039/D1CC04765E

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