Herein we report the original Ba10Fe7.75Zn5.25S18Si3O12 oxysulfide which crystallizes in a new structural type. Contrary to the usual oxychalcogenides, it crystallizes with a non-centrosymmetric 3D spatial network structure built from large magnetic clusters consisting of twelve (Fe2+/3+/Zn)S3O tetrahedra decorating a central Fe2+S6 octahedron and exhibiting a spin glass state.
B. Almoussawi, A. M. Arevalo-Lopez, P. Simon and H. Kabbour, Chem. Commun., 2021, 57, 11859 DOI: 10.1039/D1CC04501F
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