Issue 79, 2021

Construction of modular Pd/Cu multimetallic chains via ligand- and anion-controlled metal–metal interactions

Abstract

The presence of Pd⋯Cu and Pd⋯Pd interactions as well as the order of metal atoms in a chain held by a modular polynucleating ligand is controlled by the coordinating ability of the anions, leading to selective formation of bi- and tetranuclear Pd/Cu and Pd4 chains. Metal–metal cooperative reactivity in these complexes was tested in Ar–O bond formation and alkyne activation.

Graphical abstract: Construction of modular Pd/Cu multimetallic chains via ligand- and anion-controlled metal–metal interactions

Supplementary files

Article information

Article type
Communication
Submitted
03 Aug 2021
Accepted
02 Sep 2021
First published
02 Sep 2021

Chem. Commun., 2021,57, 10206-10209

Construction of modular Pd/Cu multimetallic chains via ligand- and anion-controlled metal–metal interactions

O. Rivada-Wheelaghan, S. Deolka, R. Govindarajan, E. Khaskin, R. R. Fayzullin, S. Pal and J. R. Khusnutdinova, Chem. Commun., 2021, 57, 10206 DOI: 10.1039/D1CC04212B

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