Issue 79, 2021
From the journal:

Chemical Communications

A Rh-substituted polyoxometalate with an acetate-modified building block {As2W22O76(CH3COO)2}†

Zhen Liu,a   Xue Zhang,a   Rong Wan,a   Huafeng Li,a   Yumei Hong,a   Pengtao Ma, ORCID logo a   Jingyang Niu ORCID logo *a  and  Jingping Wang ORCID logo *a  

* Corresponding authors

a Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P. R. China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: +86-371-23886876

Abstract

The first example of Rh-substituted organic–inorganic hybrid arsenotungstate [H2N(CH3)2]8{[Na(H2O)4]NaAs2W22(CH3COO)2O76 Rh2(N(CH3)2)2}·H2O (1) synthesised in an aqueous solution by the conventional method is reported. Two [Rh(N(CH3)2)]3+ fragments are imbedded into the vacancy of the [NaAs2W22(CH3COO)2O76]15− unit by Rh–As bonds [2.439(1) Å], which are observed in POM chemistry for the first time.

Graphical abstract: A Rh-substituted polyoxometalate with an acetate-modified building block {As2W22O76(CH3COO)2}

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Article information

DOI
https://doi.org/10.1039/D1CC03646G
Article type
Communication
Submitted
07 Jul 2021
Accepted
24 Aug 2021
First published
24 Aug 2021

Chem. Commun., 2021,57, 10250-10253

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A Rh-substituted polyoxometalate with an acetate-modified building block {As2W22O76(CH3COO)2}

Z. Liu, X. Zhang, R. Wan, H. Li, Y. Hong, P. Ma, J. Niu and J. Wang, Chem. Commun., 2021, 57, 10250 DOI: 10.1039/D1CC03646G

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