Issue 68, 2021
From the journal:

Chemical Communications

Construction of an iminoketenylidene†

Liam K. Burt ORCID logo a  and  Anthony F. Hill ORCID logo *a  

* Corresponding authors

a Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia
E-mail: a.hill@anu.edu.au

Abstract

The new isonitrile-μ-carbido complexes [WPt(μ-C)Br(CNR)(PPh3)(CO)2(Tp*)] (R = C6H2Me3-2,4,6, C6H3Me2-2,6; Tp* = hydrotris(dimethylpyrazolyl)borate) rearrange irreversibly in polar solvents to provide the first examples of iminoketenylidene (CCNR) complexes.

Graphical abstract: Construction of an iminoketenylidene

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Article information

DOI
https://doi.org/10.1039/D1CC03310G
Article type
Communication
Submitted
22 Jun 2021
Accepted
20 Jul 2021
First published
20 Jul 2021

Chem. Commun., 2021,57, 8480-8483

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Construction of an iminoketenylidene

L. K. Burt and A. F. Hill, Chem. Commun., 2021, 57, 8480 DOI: 10.1039/D1CC03310G

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