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Issue 56, 2021
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Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln4Zn6} secondary building units

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Abstract

3d–4f heterometallic supertetrahedral clusters with the formula of Ln4Zn66-O)L4(CH3COO)6(NO3)4(CH3OH)4(H2O)2 (1-Ln, Ln = Eu, Gd, Tb, H3L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) have been successfully introduced as stable secondary building units (SBUs) to construct new cluster-organic frameworks with tunable emission, demonstrating a promising strategy for developing new optical materials.

Graphical abstract: Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln4Zn6} secondary building units

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Supplementary files

Article information


Submitted
25 May 2021
Accepted
14 Jun 2021
First published
14 Jun 2021

Chem. Commun., 2021,57, 6927-6930
Article type
Communication

Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln4Zn6} secondary building units

R. Ge, J. Liu, X. Li, L. Li, Y. Sun, Z. Li, X. Li and S. Zheng, Chem. Commun., 2021, 57, 6927 DOI: 10.1039/D1CC02727A

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