Facile treatment tuning the morphology of Pb with state-of-the-art selectivity in CO2 electroreduction to formate

Abstract

This study presents a facile treatment to modify the commercial irregular shaped polycrystalline Pb into well-defined octahedral Pb with unique Pb(111) facets. Efficient, selective, and stable electrochemical reduction of CO₂ toward formate has been achieved on the treated Pb electrode. The faradaic efficiency of formate production from the CO₂RR is 98.03%, which is the highest reported to date. The results from the combination of theoretical calculations and experimental tests demonstrate that the enhanced catalytic performance on the treated Pb electrode stems from the electrode morphology characterized by a unique Pb(111) surface with lower Gibbs free energies (ΔG) for the formation of intermediate OCHO*.