Ba2BS3Cl and Ba5B2S8Cl2: first alkaline-earth metal thioborate halides with [BS3] units

Jiazheng Zhou; Yu Chu; Junjie Li; Shilie Pan

doi:10.1039/D1CC01510A

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Ba₂BS₃Cl and Ba₅B₂S₈Cl₂: first alkaline-earth metal thioborate halides with [BS₃] units†

Jiazheng Zhou,‡^a Yu Chu,‡^ab Junjie Li*^ab and Shilie Pan

*^ab

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: lijunjie@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Ba₂BS₃Cl and Ba₅B₂S₈Cl₂ have been synthesized by using PbCl₂ as the flux and source of halogen. The two compounds show 3D network structures built by isolated [BS₃] units with different Ba–S–Cl groups. This work enriches the structural diversity of boron chemistry and provides an insight into the synthesis of thioborates.

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Article information

DOI: https://doi.org/10.1039/D1CC01510A
Article type: Communication
Submitted: 19 Mar 2021
Accepted: 24 May 2021
First published: 26 May 2021

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Chem. Commun., 2021,57, 6440-6443

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Ba₂BS₃Cl and Ba₅B₂S₈Cl₂: first alkaline-earth metal thioborate halides with [BS₃] units

J. Zhou, Y. Chu, J. Li and S. Pan, Chem. Commun., 2021, 57, 6440 DOI: 10.1039/D1CC01510A

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Chemical Communications