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Brønsted acid catalyzed radical addition to quinone methides

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Abstract

A fundamental quest for alkyl radical generation under mild conditions through photoinduced Brønsted acid catalysis is addressed. The optimized protocol does not require any organic dyes or transition metal photocatalyst. Under blue light irradiation with diphenyl phosphate as a catalyst and dihydropyridine derivatives as a radical source, functionalized arylmethane derivatives are obtained in high yield.

Graphical abstract: Brønsted acid catalyzed radical addition to quinone methides

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Article information


Submitted
11 Mar 2021
Accepted
16 Apr 2021
First published
16 Apr 2021

Chem. Commun., 2021, Advance Article
Article type
Communication

Brønsted acid catalyzed radical addition to quinone methides

S. S. Patel, D. Kumar and C. B. Tripathi, Chem. Commun., 2021, Advance Article , DOI: 10.1039/D1CC01335A

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