Issue 34, 2021
From the journal:

Chemical Communications

Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(vi) centres of Ru(ii)–Mo(vi) dyads†

Maryam Nazari Haghighi Pashaki, ORCID logo a   Tae-Kyu Choi, ORCID logo b   Egmont J. Rohwer,a   Thomas Feurer,a   Anne-Kathrin Duhme-Klair, ORCID logo *c   Wojciech Gawelda ORCID logo *def  and  Andrea Cannizzo ORCID logo *a  

* Corresponding authors

a Institute of Applied Physics, University of Bern, Sidlerstrasse 5, Bern, Switzerland
E-mail: andrea.cannizzo@iap.unibe.ch

b European XFEL, Holzkoppel 4, 22869 Schenefeld, Germany

c Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
E-mail: anne.duhme-klair@york.ac.uk

d Departamento de Química, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus Cantoblanco, 28049 Madrid, Spain
E-mail: wojciech.gawelda@uam.es

e Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanociencia), Campus Cantoblanco, 28049 Madrid, Spain

f Faculty of Physics, Adam Mickiewicz University, ul. Uniwersytetu Poznańskiego 2, 61-614 Poznan, Poland

Abstract

Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedly photo-activated in ps timescales. One-photon absorption generates an excited state where both photo-oxidized and photo-reduced catalytic centres are activated simultaneously and independently.

Graphical abstract: Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(vi) centres of Ru(ii)–Mo(vi) dyads

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Article information

DOI
https://doi.org/10.1039/D1CC00750E
Article type
Communication
Submitted
08 Feb 2021
Accepted
19 Mar 2021
First published
23 Mar 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 4142-4145

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Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(VI) centres of Ru(II)–Mo(VI) dyads

M. Nazari Haghighi Pashaki, T. Choi, E. J. Rohwer, T. Feurer, A. Duhme-Klair, W. Gawelda and A. Cannizzo, Chem. Commun., 2021, 57, 4142 DOI: 10.1039/D1CC00750E

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