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Functional ligand directed assembly and electronic structure of Sn18-oxo wheel nanoclusters

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Abstract

A bilayer hexagonal wheel Sn18-oxo cluster, as the largest tin-oxo wheel to date, was successfully constructed by structural directing of organic ligands. Moreover, the ligands show important effects on the electronic structure and third-order nonlinear optical properties of the Sn18-oxo wheel, which is demonstrated by detailed theoretical calculations.

Graphical abstract: Functional ligand directed assembly and electronic structure of Sn18-oxo wheel nanoclusters

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Article information


Submitted
04 Feb 2021
Accepted
16 Apr 2021
First published
17 Apr 2021

Chem. Commun., 2021, Advance Article
Article type
Communication

Functional ligand directed assembly and electronic structure of Sn18-oxo wheel nanoclusters

Y. Zhu, Q. Li, D. Li, J. Zhang and L. Zhang, Chem. Commun., 2021, Advance Article , DOI: 10.1039/D1CC00651G

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