The energy barrier and hysteresis temperature in two benchtop-stable D5h-symmetry HoIII single-ion magnets were significantly enhanced via the variation of the halogen anion. The coexistence of a high energy barrier of 418 K and hysteresis temperature of 15 K was observed in the bromide-ion containing HoIII single-ion magnet.
K. Jia, X. Meng, M. Wang, X. Gou, Y. Wang, N. Xu, W. Shi and P. Cheng, Chem. Commun., 2021, 57, 3607 DOI: 10.1039/D1CC00582K
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