A non-isolated pentagon rule C82 cage stabilized by a stretched Sc3N cluster

Min Guo; Xiaomeng Li; Yang-Rong Yao; Jiaxin Zhuang; Qingyu Meng; Yingjing Yan; Xinye Liu; Ning Chen

doi:10.1039/D1CC00328C

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A non-isolated pentagon rule C₈₂ cage stabilized by a stretched Sc₃N cluster†

Min Guo,‡^a Xiaomeng Li,‡^a Yang-Rong Yao,^b Jiaxin Zhuang,^a Qingyu Meng,^a Yingjing Yan,^a Xinye Liu^a and Ning Chen

*^a

Author affiliations

* Corresponding authors

^a College of Chemistry, Chemical Engineering and Materials Science, and State Key Laboratory of Radiation Medicine and Protection, Soochow University, Suzhou, Jiangsu 215123, P. R. China
E-mail: chenning@suda.edu.cn

^b Department of Chemistry, University of Texas at El Paso, 500 W University Avenue, El Paso, Texas 79968, USA

Abstract

A novel cluster fullerene, Sc₃N@C_s(39 663)-C₈₂, has been synthesized and characterized. Crystallograpic charaterization unambiguously determines the non-IPR cage structure of C_s(39 663)-C₈₂. Structural analyses further reveal that the Sc₃N cluster is notably stretched to facilitate the interaction with the non-IPR fullerene cage.

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Article information

DOI: https://doi.org/10.1039/D1CC00328C
Article type: Communication
Submitted: 19 Jan 2021
Accepted: 19 Mar 2021
First published: 22 Mar 2021

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Chem. Commun., 2021,57, 4150-4153

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A non-isolated pentagon rule C₈₂ cage stabilized by a stretched Sc₃N cluster

M. Guo, X. Li, Y. Yao, J. Zhuang, Q. Meng, Y. Yan, X. Liu and N. Chen, Chem. Commun., 2021, 57, 4150 DOI: 10.1039/D1CC00328C

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Chemical Communications