The catalytic diversity of heme enzymes is a perpetuating pursuit for biomimetic chemistry, but heme nanozymes exhibit catalytic activity only reminiscent of peroxidases. Miraculously, the oxidase-like catalytic function of a heme cofactor is elicited with the help of gold nanoparticles (AuNPs) by maintaining heme with a low-valence state (ferrous) in a confined configuration.
Y. Liu, Z. Chen, Z. Shao and R. Guo, Chem. Commun., 2021, 57, 3399 DOI: 10.1039/D1CC00279A
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