The formation of catalytically active alkyl-Ni(I) complexes by comproportionation of diorgano-Ni(II) precursors and Ni(0) species proceeds easily through triplet states by alkyl ligand exchange. The process involves inversion of the configuration at the carbon that is transferred.
M. T. Quirós, D. Collado-Sanz, E. Buñuel and D. J. Cárdenas, Chem. Commun., 2021, 57, 2424 DOI: 10.1039/D1CC00203A
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