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A new class of anionic metallohelicates based on salicylic and terephthalic acid units, accessible in solution and by mechanochemistry

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Abstract

We present a new class of anionic metallohelicates based on an abundant, industrially relevant salicylic acid derivative, leading to discrete double and triple-stranded architectures based on divalent and trivalent metals (Cu2+, Fe3+, respectively). The ability to assemble the metallohelicates in a solvent-free environment presents the opportunity to develop an inexpensive and environmentally-friendly design of helicate materials.

Graphical abstract: A new class of anionic metallohelicates based on salicylic and terephthalic acid units, accessible in solution and by mechanochemistry

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Article information


Submitted
16 Dec 2020
Accepted
15 Apr 2021
First published
16 Apr 2021

Chem. Commun., 2021, Advance Article
Article type
Communication

A new class of anionic metallohelicates based on salicylic and terephthalic acid units, accessible in solution and by mechanochemistry

J. Do, H. M. Titi, L. A. Cuccia and T. Friščić, Chem. Commun., 2021, Advance Article , DOI: 10.1039/D0CC08180A

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