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Solvophobic interaction promoted supramolecular helical assembling of building blocks of weak intermolecular halogen bonding

Abstract

We report supramolecular helical assembling in water of β-turn structured bis(N-amidothioureas) containing Br-substitutes of moderate halogen bonding ability, promoted by stronger hydrophobic interaction. The helical polymers show an unusual negative nonlinear CD-ee dependence.

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Article information


Submitted
11 Dec 2020
Accepted
13 Jan 2021
First published
13 Jan 2021

Chem. Commun., 2021, Accepted Manuscript
Article type
Communication

Solvophobic interaction promoted supramolecular helical assembling of building blocks of weak intermolecular halogen bonding

X. Yan, J. Cao, Y. Zhang, P. Weng, D. Miao, Z. Zhao, Z. Li and Y. Jiang, Chem. Commun., 2021, Accepted Manuscript , DOI: 10.1039/D0CC08041A

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