Issue 13, 2021
From the journal:

Chemical Communications

Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights†

Massimo Christian D'Alterio, ORCID logo a   Claudio De Rosa ORCID logo a  and  Giovanni Talarico ORCID logo *a  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università degli Studi di Napoli Federico II, Complesso Monte S’Angelo, Via Cintia, Napoli, Italy
E-mail: giovanni.talarico@unina.it

Abstract

The mechanism(s) for the formation of syndiotactic PLA by the ROP of meso-LA by a chiral-Al-complex are disclosed by DFT calculations. The contributions toward stereoselectivity have been analyzed confirming the peculiar chiral recognition for stereocontrolled ROP polymerization.

Graphical abstract: Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights

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Article information

DOI
https://doi.org/10.1039/D0CC07787A
Article type
Communication
Submitted
28 Nov 2020
Accepted
05 Jan 2021
First published
05 Jan 2021

Chem. Commun., 2021,57, 1611-1614

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Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights

M. C. D'Alterio, C. De Rosa and G. Talarico, Chem. Commun., 2021, 57, 1611 DOI: 10.1039/D0CC07787A

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