Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material

Zhen Li; Julio Fraile; Clara Viñas; Francesc Teixidor; José G. Planas

doi:10.1039/D0CC07393H

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Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material†

Zhen Li,^a Julio Fraile,^a Clara Viñas,

^a Francesc Teixidor

^a and José G. Planas

*^a

Author affiliations

* Corresponding authors

^a Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, Bellaterra 08193, Spain
E-mail: jginerplanas@icmab.es

Abstract

Post-synthetic modification of a dynamic carborane-based soft porous crystal (1 ⊃ DMF) by in situ polymerization of pyrrole to polypyrrole (PPy) provided a permanently porous MOF/polypyrrole hybrid composite material that did not show the dynamic behavior of the mother MOF. Apart from stability, the introduction of conductive PPy in the composite material brings new properties to the otherwise non-conductive MOF.

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Article information

DOI: https://doi.org/10.1039/D0CC07393H
Article type: Communication
Submitted: 10 Nov 2020
Accepted: 31 Jan 2021
First published: 03 Feb 2021
This article is Open Access

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Chem. Commun., 2021,57, 2523-2526

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Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material

Z. Li, J. Fraile, C. Viñas, F. Teixidor and J. G. Planas, Chem. Commun., 2021, 57, 2523 DOI: 10.1039/D0CC07393H

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Chemical Communications

Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material†

Abstract

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Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material

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